Analysis of Characteristics of a 5 KW Power Plant Based on Solid Oxide Fuel Cells in Four Modes

Analysis of Characteristics of a 5 KW Power Plant Based on Solid Oxide Fuel Cells in Four Modes

J. Volkova V. Munts N. Plotnikov J. Munts

Department of Heat Power Engineering and Heat Engineering, Ural Federal University, Russia

Ural Industrial Company, Russia

Department of Control Systems in Power Engineering and Production Plants, Ural Federal University, Russia

Page: 
60-69
|
DOI: 
https://doi.org/10.2495/EQ-V2-N1-60-69
Received: 
N/A
| |
Accepted: 
N/A
| | Citation

OPEN ACCESS

Abstract: 

The paper presents the results of testing a 5 kW power plant based on solid oxide fuel cells (SOFC) with natural gas serving as fuel, equipped with a steam reformer combined with a burner. It includes a diagram of the power plant and a result analysis procedure based on heat and mass balances elaborated for the reformer, SOFC stack, catalytic burner and heat exchanger. The experimental findings were used to calculate the actual ratios of fuel utilization, oxygen consumption from cathode air in the electrochemical generator using two methods (heat and energy balances and Faraday’s law). A comparison of the results of the two methods revealed a small error, which was observed mainly in the second mode (60%).

Parameters of the power plant by ‘UIC’ LLC were reviewed at four steady running modes: 40% of SOFC’s power utilization (2 kW), 60% (3 kW), 90% (4.5 kW) and at the peak mode of 110% (5.4 kW), where the consumption exceeds the rated power by 10%.

Calculation of the equilibrium composition of conversion products, at temperatures (t3) registered at the reformer’s outlet, allowed the formula for the natural gas reforming reaction to be obtained.

A simplified method of calculating the composition of the natural gas steam reforming products is described; the results are compared with calculations made in the program Gaseq, using the software package Mathcad for the solution of nonlinear equations.

Analysis of the results showed the effectiveness of a simplified method at temperatures above 800°C; in that temperature range, this method has an error of less than 0.5%, which is sufficient for using in practice.

Keywords: 

result of experiments, simplified method of calculating, solid oxide fuel cells, steam reforming of natural gas, studying of performance

  References

[1] Baskakov, A.P. & Volkova, Y.V., Physics and Chemistry of Thermal Processes: Textbook, Moscow: Teplotehnik, 2013.

[2] Chang, T.G., Lee, S.M., Ahn, K.Y. & Kim, Y., An experimental study on the reaction characteristics of a coupled reactor with a catalytic combustor and a steam reformer for SOFC systems. International Journal of Hydrogen Energy, 37, pp. 3234–3241, 2012. http://dx.doi.org/10.1016/j.ijhydene.2011.11.076

[3] Korovin, N.V., Sedlov, A.S., Slavnov, Yu.A. & Burov, V.D., Calculating the efficiency of a hybrid power station based on a high-temperature power cell. Teploenergetika.  2,pp. 49–53, 2007.

[4] Lykova, S.A., High-efficiency hybrid power facilities based on fuel cells. Teploenerge- tika, 15, pp. 50–55, 2002.

[5] Korovin, N.A., Fuel Cells and Electrochemical Power Facilities, Moscow: MPEI, p. 280, 2005.

[6] Kasilova, E.V., Analytical and theoretical study of transfer processes in a solid oxide fuel cell: Candidate dissertation in Engineering Science. Moscow: MPEI, 2015.

[7] Boiler Thermal Design (normative method). 3rd edn., revised and enlarged. St. Peters- burg: NPO CKTI, 1998.

[8] Baskakov, A.P., Volkova, Yu.V. & Plotnikov, N.S., Optimum rate of chemical regenera- tion in solid oxide fuel cells. Engineering and Physics Journal, 78(4), pp. 741–750.

[9] Leibush, A.G. (ed), Production of Process Gas for Synthesizing NH3 and Methanol from Hydrocarbon Gases, Moscow: Himiya, 1971.

[10] Baskakov, A.P., Heating and Cooling Metals in a Bubbling Layer, Moscow: Metal- lurgiya, 1974.

[11] Ravdel, K.P. & Mischenko, A.A. (eds), Critical Tables. Quick Reference Book, 7th edn., Leningrad: Himiya, 1974.

[12] Bogdanov, S.N., Burtsev, S.I., Ivanov, O.P. & Kupriyanova, A.V. Refrigeration Appliances and Engineering. Air Conditioning. Properties of Substances: Reference Book, 4th edn., revised and enlarged. St. Petersburg, 1999.