Effect of Growth Solution Concentration on the Performance of Boron Doped ZnO Dye-sensitized Solar Cell (DSSC)

Effect of Growth Solution Concentration on the Performance of Boron Doped ZnO Dye-sensitized Solar Cell (DSSC)

M.Y.A. RahmanA. A. UmarL. Roza S.A.M. Samsuri M.M. Salleh I. Iwantono Tugirin Tugirin 

Institute of Microengineering and Nanoelectronics (IMEN), Universiti Kebangsaan Malaysia (UKM), Bangi, 43600, Selangor, Malaysia

Department of Physics, Faculty of Mathematics and Natural Sciences, Universitas Riau, Pekanbaru, 28131, Indonesia

Corresponding Author Email: 
mohd.yusri@ukm.edu.my, akrajas@ukm.edu.my
6 July 2015
1 September 2015
20 November 2015
| Citation

Synthesis parameter plays important role in modifying physical property of metal oxide films which serve as photoanode in dye-sensitized solar cell (DSSC). This paper reports the synthesis of boron doped ZnO nanostructures via seed mediated growth hydrothermal technique and their application as photanode in DSSC. The growth process was carried out at various solution concentrations, 0.1, 0.2, 0.3 and 0.4 M. The solution contains 1 % wt. dimethyl borate as boron source, hexamethylenetetramine (HMT) surfactant and zinc nitrate (Zn(NO3)2). The samples are crystalline with wurtzite phase. The morphological shape of the samples changes with the growth solution concentration. The optical absorption increases as the concentration increases. However, the band gap does not significantly change with the concentration. The DSSC utilizing the ZnO sample prepared at 0.1 M solution performs the best photovoltaic parameters with the JSC of 0.969 mA cm-2, FF of 0.48 and η of 0.222%, respectively since it shows the highest absorption and lowest photoluminescence in visible region.


boron, dye-sensitized solar cell, hydrothermal, ZnO

1. Introduction
2. Experimental
3. Results and Discussion
4. Conclusions

This work was supported by The Ministry of higher Education of Malaysia under research grant FRGS/2/2013/SG02/UKM/02/5 and FRGS/2/2013/SG02/UKM/02/8.

This work was also supported by The Ministry of Research, Technology and Higher Education of Indonesia under research grant KLN (International Research Collaboration and Scientific Publication 2015) contract no. 550/UN.19.1/LPPM/2015" in the section of acknowledgements.


[1] Law M, Greene LE, Radenovis A, Kuykendall T, Liphardt J, Yang P, J Phys Chem B, 110, 22652 (2006).

[2] Samsuri SAM, Rahman MYA, Umar AA, Salleh MM, J Mat Sci., Mat Elect., 26, 4936 (2015).

[3] Karuppuchamy S, Nonomura K, Yoshida T, Sugiura T, Minou-ra H, Sol State Ion., 151, 19 (2002).

[4] Ameen S, Akhtar MS, Seo H-K, Kim YS, Shin HS, Chem Eng J., 187, 351 (2012).

[5] Tubtimtae A, Lee M-W, Superlatt Microstruc., 52, 987 (2012).

[6] Zhang J, Peng W, Chen Z, Chen H, Han L, J Phys Chem C, 116, 19182 (2012).

[7] Zhang JC, Han ZY, Li QY, Yang XY, Yu Y, Cao WL, J Phys Chem Sol., 72, 1239 (2011).

[8] Rahman MYA, Umar AA, Saad SKM, Salleh MM, Ishaq A, J New Mater Electrochem System., 17, 33 (2014).

[9] Ma T, Akiyama M, Abe E, Nano Letter, 5, 2543 (2005).

[10]Lim CK, Huang H, Chow CL, Tan PY, Cheng X, Tse MS, Tan OK, J Phys Chem C, 116, 19659 (2012).

[11]Tang Y-B, Lee C-S, Xu J, Liu Z-T, Chen Z-H, He Z, Cao Y-L, Yuan G, Song H, Chen L, Luo L, Cheng H-M, Zhang W-J, Bello I, Lee S-T, ACS NANO, 4, 3482 (2010).

[12]Pawar BN, Cai G, Ham D, Mane RS, Ganesh T, Ghule A, Sharma R, Jadhava KD, Han SH, Solar Energy Mater Solar Cells, 93, 524 (2009).

[13]Kumar V, Singh N, Kumar V, Purohit LP, Kapoor A, Ntwaeaborwa OM, Swart HC, J App. Phys, 114, 134506 (2013).

[14]Rusdi R, Rahman A, Mohamed NS, Kamarudin N, Kamarul-zaman N, Powder Tech, 210, 18 (2011).

[15]Iwantono I, Nurwidya W, Lestari LR, Naumar FY, Nafisah S, Umar AA, Rahman MYA, Salleh MM, J Solid State Electro-chem, 19, 1217 (2015).

[16]Roza L, Rahman MYA, Umar AA, Salleh MM, J Alloys Comp, 618, 153 (2015).

[17]Rahman MYA, Roza L, Umar AA, Salleh MM, J Alloys Comp., 648, 86 (2015).