Water Quality Index (WQI) for Main Water Treatment Plants in Basra City, Iraq

Water Quality Index (WQI) for Main Water Treatment Plants in Basra City, Iraq

Ahmed S. Al Chalabi* Saja M. Naeem Raad J. Alkhafaji

Department of Environmental and Pollution Technical Engineering, Basrah Engineering Technical College, Southern Technical University, Al Basra 61001, Iraq

Corresponding Author Email: 
ahmed.sadiq@stu.edu.iq
Page: 
1407-1416
|
DOI: 
https://doi.org/10.18280/ijdne.180614
Received: 
12 May 2023
|
Revised: 
6 September 2023
|
Accepted: 
12 October 2023
|
Available online: 
26 December 2023
| Citation

© 2023 IIETA. This article is published by IIETA and is licensed under the CC BY 4.0 license (http://creativecommons.org/licenses/by/4.0/).

OPEN ACCESS

Abstract: 

The Water Quality Index (WQI), a paramount tool for appraising potable water quality, significantly influences human health and survival. It is an index that quantifies the cumulative effect of various water quality parameters, which are integral in the computation of the index. This study was undertaken to calculate the WQI of ten water treatment facilities in Basra city, for the period spanning January to December 2021, through an evaluation of the physical and chemical attributes of the raw and treated water. Regrettably, it was found that none of the treatment plants under study produced water deemed fit for human consumption. Notably, only the Al-Garmma 1 plant was classified as delivering water of poor quality, while the remaining facilities produced water of either very poor quality or, more alarmingly, unfit for human consumption. This constitutes a grave public health concern for the residents of Basra Governorate. The findings necessitate the exploration of alternative, superior treatment methodologies to those currently employed in these facilities. It is a stark reminder of the critical role played by water treatment infrastructure in safeguarding public health and underscores the urgent need for enhancements in treatment processes in the Basra region. This study serves as a stepping-stone towards reforming water treatment practices, ultimately contributing to improved public health outcomes.

Keywords: 

Basra city, Shatt Al-Arab River, water quality parameters, water treatment plant, WQI

1. Introduction

Water, an elemental resource crucial to sustaining life, constitutes approximately 71% of the Earth's surface and is indispensable to all known life forms [1]. Despite its relative abundance, around a third of the world's population endures a severe scarcity of drinkable water, a situation exacerbated chiefly in underdeveloped countries due to rapid population growth and concomitant large-scale agricultural and economic expansion [2]. With 90% of polluted water being discharged into rivers and streams [3], the mounting demand for fresh water has inevitably rendered water management a pressing global concern [4]. Regular monitoring of water quality is integral to the sustainable management of water resources [5]. Water quality information delineates the biological, chemical, and physical constituents of water and their interactions, thereby facilitating its appropriate use [6]. The purification process, necessary to render water fit for human consumption, requires removal of undesirable physical elements such as taste and odor, as well as chemical and microbiological contaminants [7]. Various treatment processes, inclusive of flocculation, sedimentation, filtration, and disinfection, are implemented in treatment plants to ensure the provision of safe water to communities [8]. The characteristics of the raw water source and the technical and operational conditions within the treatment plant units largely determine the quality of the treated water [9]. Regular evaluation of the operation of water treatment plants, via monitoring of the quality of treated water, is crucial to ensure compliance with legal requirements [10]. Assessment of raw and treated water quality typically involves physical, chemical, and biological parameters [11].

The Water Quality Index (WQI) is a mathematical tool that synthesizes a significant volume of water data (standard parameters) into a single number [12], serving as a pivotal and widely employed technique in ascertaining water quality and requisite treatment [13]. This index enables categorization of water for various uses and provides a standard for evaluating management strategies [14]. The Weighted Arithmetic Index Method (WAWQI), employed in this study, is a popular approach yielding practical and reasonable results.

Basra, a city in southern Iraq, predominantly relies on the Shatt al-Arab River for its water supply, which also caters to agricultural, industrial, and miscellaneous uses. Most of Basra's water treatment plants, classified as classic plants treating surface water via coagulation, flocculation, sedimentation, and filtration, are situated alongside the Shatt al-Arab River [15]. Numerous studies have evaluated these plants' efficacy, either by assessing the quality of water they produce or by examining the efficiency of their individual treatment units.

The primary objectives of this study include evaluating the physical and chemical properties of the river water (raw water) and the water output from the treatment plants to determine the water quality of the Shatt al-Arab River and the treated water produced by these plants, using the WQI as a benchmark.

2. Study Area

Iraq's main resource is surface water. Iraq is dependent on the waters of the Tigris and Euphrates and their tributaries, as well as the Shatt al-Arab river, which is made up of the Tigris and Euphrates' confluence in the town of Qurna in the Basra province (see Figure 1). With a length of 192 km, the water from the Shatt al-Arab river is discharged into the Arabian Gulf. Depending on the amount of water originating from Turkey and Syria, as well as the amount of rain and snow that falls, the amount of water varies from year to year [16].

Figure 1. Locations of water treatment plants in Basra city

Table 1. Details of water treatment plants

Water Treatment Plant Name

Location

Water Treatment Plant Type

Longitude

Latitude

Mihejran

47°51'14.49"E

30°26'58.30"N

Multiple package units

Al Garmma 1

47°44'45.44"E

30°34'20.64"N

Multiple package units

Al Jubila 1

47°48'46.42"E

30°33'1.11"N

Conventional

Al Bradiah 1

47°51'20.00"E

30°30'9.18"N

Conventional

Shatt Al Arab

47°52'24.15"E

30°32'49.95"N

Multiple package units

Al Zubair

47°46'32.25"E

30°13'14.34"N

Conventional

Al Fao

48°26'53.33"E

29°59'24.62"N

Conventional

Al Nashwa

47°39'27.03"E

30°45'22.20"N

Conventional

Al Qurna

47°20'17.68"E

30°58'27.00"N

Conventional

Al Ribat

47°49'51.60"E

30°32'9.60"N

Multiple package units

All water treatment plants in Basra were constructed along the banks of the Shatt al-Arab river because it is the city's primary source of fresh water. To determine the quality of the water produced by these plants and its appropriateness for drinking [17]. The city center and all of its associated districts were represented by the ten largest water treatment plants in Basra Governorate (Table 1), which were chosen for analysis of the water's chemical and physical properties and calculation of the water quality index for each of these plants.

3. Materials and Methods

To analyze the water provided to Basra for the time period from January 2021 to December 2021, ten water treatment plants in the governorate's center and its environs were chosen, and samples of the water leaving these plants were taken. Every month (Certain days of the month), water samples were collected for each of the stations listed in Table 1 in plastic bottles, which were then put in a cooler box and delivered to the lab.

Each sample was examined to determine 12 parameters, including pH, turbidity, Total Hardness (TH), electrical conductivity (EC), alkalinity, calcium (Ca), magnesium (Mg), chloride (Cl), sulfate (SO4), Total Dissolved Solids (TDS), sodium (Na) and potassium (K) using guidelines from Examination of Water and Wastewater [18].

3.1 Water Quality Index (WQI)

One of the most common methods for expressing water quality is the WQI. We can determine the water quality and the necessary treatment procedures by knowing the value of the WQI [12]. A water quality index is a mathematical technique for expressing water quality by combining a lot of measurable water data into a single value. The WQI is a tool that may be used to compare the quality of water from various sources and to provide a rough understanding of any potential water issues in a given location [19].

Several national and international organizations have developed various water quality indexes [20]. In this study, the weighted arithmetic index approach of the parameter was implemented from numerous publications [21]. The most frequently measured water quality variables are used in the Weighted Arithmetic Water Quality Index Method, which categorizes the water quality according to the level of purity [22]. Twelve physicochemical factors (pH, EC, TDS, K, Na, Mg, Ca, TH, Cl, turbidity, alkalinity, and SO4) were taken into account in a four-stage method to calculate the WQI for the suggested case study.

Step 1: Calculating the inverse of the standardized maximum concentration (Cn) to obtain the proportionality constant "K" in Eq. (1). The number of parameters used in the investigation affects the value of k [23].

$K=\frac{1}{\sum_{n=1}^m \frac{1}{C_n}}$        (1)

Step 2: Using Eq. (2), the relative weight (Wn) was then calculated.

$W_n=\frac{K}{C_n}$       (2)

Step 3: The third step was utilizing Eq. (3) to generate the quality rating scale (Qn) for each parameter.

$Q_n=\left[\frac{S_n-S_0}{C_n-S_0}\right] * 100$         (3)

where,

Sn is the measured concentration of each parameter.

S0 is the ideal value of each parameter in pure water.

S0=0 (except pH =7.0 and Dissolved Oxygen = 14.6 mg/l).

Step 4: Lastly, the water quality index (WQI) was calculated using the Eq. (4).

$W Q I=\frac{\sum W_n * Q_n}{\sum W_n}$          (4)

A comparison is made between the value of the water quality index and Table 2, which is separated into stages based on water quality, from excellent to non-potable [24].

Table 2. Types of WQI [24]

Type of Water

WQI Range

Grinding

Possible Usage

Excellent water

0 - 25

A

Drinking, Irrigation and Industrial

Good water

26 - 50

B

Domestic, Irrigation and Industrial

Poor water

51 - 75

C

Irrigation and Industrial

Very poor water

76 - 100

D

Irrigation

Unfit for consumption

˃ 100

E

Restricted use for Irrigation

4. Results and Discussion

In this study, Appendixes 1 and 2 display the statistical analysis of physical and chemical parameters of treated water from 10 Basra water treatment plants for the time period of January 2021 to December 2021. The parameters measured at these stations' maximum, minimum, mean, and standard deviation are displayed in Appendixes 1 and 2, along with a comparison to the WHO's [25] and Iraqi standards' [26] upper and lower bounds (Table 3).

Table 3. The classification of water based on Iraqi and WHO standards [25, 26]

Parameter

Iraq Standard

WHO Standard

Unit

pH

6.5 - 8.5

6.5 - 8.6

­

Electrical Conductivity (EC)

400

400

µs/cm

Turbidity

5

­

NTU

Alkalinity

20

50 - 150

mg/l

Total Hardness (TH)

500

500

mg/l

Total Dissolved Solids (TDS)

1000

1000

mg/l

Calcium (Ca)

100

75

mg/l

Sodium (Na)

200

200

mg/l

Potassium (K)

12

12

mg/l

Chloride (Cl)

250

250

mg/l

Magnesium (Mg)

50

50

mg/l

Sulfate (SO4)

250

250

mg/l

Figure 2 illustrates the pH range of the water leaving the water treatment plants used in this study. The Mihejran plant had the lowest pH levels, at 6.9, while the Al-Nashwa plant had the highest pH levels, at 8.2. All pH measurements fall within the acceptable levels established by the World Health Organization and Iraqi guidelines (see Table 3).

Electrical conductivity (EC) is a measure of positive ions (cations), which greatly affect the taste and thus the acceptability and palatability of water by the consumer [27]. EC is a metric that is assessed for an indirect indication of water salinity in the water and agriculture sectors [28]. This number represents the total amount of dissolved salts [29]. EC is influenced by temperature, ionic concertation, and the types of ions that are present in water. Therefore, EC offers a qualitative evaluation of the water quality [30]. Figure 3 illustrates the EC of treated water from all water treatment plants, which is greater than the permitted limits of the Iraqi standard and the WHO (see Table 3).

Colloidal and ultra-fine dispersions in water bodies are the main cause of turbidity. Drinking water quality in the distribution network is likely to deteriorate as a result of rising microbial counts, raised iron concentrations, or rising turbidity, all of which have an impact on the taste, odor, and color of water. Pathogens and opportunistic microorganisms can find refuge in turbidity [27]. In Figure 4, the results showed a variance in the amount of turbidity in the treated water from the treatment plants in this study, with the biggest amounts coming from the Al-Fao plant (24.9 NTU) and the Al-Qurna plant (24 NTU), and the lowest amounts from the Al-Nashwa plant 1 NTU (see Appendixes 1).

Alkalinity is a sign of a water's capacity to neutralize acids that have been added to it. This parameter therefore represents the buffering capacity of waters. The three most significant substances that can influence the alkalinity of water are dissolved hydroxides, carbonates, and bicarbonates [31]. Drinking water guidelines state that a water supply should have moderate amounts of alkalinity to reduce the corrosive effects of acidity [32]. Figure 5 demonstrates that, save from the Al-Ribat plant for Dec. 2021 and the Al-Zubair plant for Sep. 2021, all of the treated water from the treatment plants has an alkalinity concentration that is higher than what is permitted by WHO and Iraqi standards (see Table 3). Since the pH did not exceed 8.3, this means that the cause of the alkalinity of the treated water from these stations are bicarbonate ions [17].

Results for the treated water in the water treatment plants in this study during the period of Jan. 2021 to Dec. 2021 showed variations in the concentrations of parameters TH, TDS, Ca, Na, K, Cl, Mg, and SO4 (see Tables 2 and 3). The data showed that the Mihejran plant had the highest concentration of TH (1880 mg/l), while the Shatt Al-Arab plant had the lowest concentration 303 mg/l (Figure 6). In addition, the Mihejran plant's treated water had the highest concentration of TDS (7158 mg/l), while the Shatt Al-Arab plant had the lowest concentration 546 mg/l (Figure 7). In Figure 8, the Mihejran plant has the highest Ca concentration (380 mg/l), while the Shatt Al Arab and Al Ribat plants have the lowest calcium concentrations (62 mg/l). In Figure 9, the Mihejran plant has the highest Na concentration (1880 mg/l) and the Shatt Al Arab plant has the lowest sodium concentration (74 mg/l) in the treated water.

Figure 2. pH value of treated water from WTPs

Figure 3. EC concentration of treated water from WTPs

Figure 4. Turbidity concentration of treated water from WTPs

Figure 5. Alkalinity concentration of treated water from WTPs

Figure 6. Total hardness concentration of treated water from WTPs

Figure 7. Total dissolved solids concentration of treated water from WTPs

Figure 8. Ca concentration of treated water from WTPs

Figure 9. Na concentration of treated water from WTPs

Figure 10. Cl concentration of treated water from WTPs

Figure 11. K concentration of treated water from WTPs

Figure 10 illustrates the difference in Cl concentrations in the treated water, with the Mihejran plant having the greatest concentration (2860 mg/l) and the Al-Ribat plant having the lowest concentration (136 mg/l). Additionally, Figure 11 demonstrates that the Al-Garmma 1 plant records the lowest K concentration (3 mg/l) and the Mihejran plant records the highest K concentration (14.6 mg/l). The treated water in the Mihejran plant has the highest level of Mg (227 mg/l), while the Mg concentration in the Shatt Al-Arab plant is the lowest (36 mg/l), according to Figure 12. The concentration of SO4 in the water from the Al-Jubaila 1 plant has the lowest concentration (971 mg/l), while the Mihejran plant has the greatest concentration (1175 mg/l), this is demonstrated in Figure 13.

4.1 WQI analysis

As shown in Tables 2 and 3, the weighted arithmetic index method was used to calculate the water quality index by measuring a few physical and chemical characteristics of raw water (incoming water) and treated water (outgoing water) at ten water treatment plants in Basra Governorate from January 2021 to December 2021. Figure 14 depicts the value of the water quality of the treatment plants used in this study, and it reveals that none of them provide water that is potable or of high quality (excellent or good). Figure 14 demonstrates the poor water quality of the Al-Garmma 1 station's treated water. very Poor water quality is provided by the Al-Jubila 1, Al-Buradiah 1, Shatt Al-Arab, Al-Zubair, Al-Nashwa, and Al-Ribat plants. The plants in Mihejran, Al-Fao, and Al-Qurna provide water that is unfit for human consumption.

Three water quality readings were taken for each research plant, and Figure 15 illustrates the considerable variation between those values over the course of a complete year from January 2021 to December 2021. The first value shows the minimum value for the quality of treated water, the second value shows the average values (mean) for the quality of treated water, and the third value displays the maximum values for the year's treatment. If the minimum value for the quality of the treated water at these stations is used, it has been shown that the majority of the plants provide good water quality, but when the maximum value is used, we discover that all of the plants are unfit for human consumption.

Figure 12. Mg concentration of treated water from WTPs

Figure 13. SO4 concentration of treated water from WTPs

Figure 14. WQI for the raw and treated water for WTPs

Figure 15. Variation of WQI for the treated water for WTPs

5. Conclusion

The current study was carried out on the primary source of raw water (Shatt Al-Arab River) and treated water for ten treatment plants in the Basra Governorate during the time period of January 2021 to December 2021. By assessing some of the raw water's and treated water's physical and chemical properties, as well as the WQI for each of these plants. The results showed that:

  • By examining some of the physical and chemical properties of the water entering each plant, it was demonstrated that the Shatt Al-Arab River's water quality is quite low. The majority of these data, including total dissolved salts, salinity, turbidity, total hardness, and elevated calcium and sulfate concentrations, were discovered to be higher than those permitted by the WHO and Iraqi regulations.
  • The Shatt al-Arab River's salinity and insufficient supply of water are the main causes of the river's water quality decline. The inputs of municipal, industrial, and agricultural wastes that are released onto the river bank are the main cause of the deterioration in water quality.
  • The results showed that the value of the WQI for all treatment plants in this study are very poor values and do not provide potable water. This has an impact on the lives of people living in Basra Governorate. As a result, it is necessary to reevaluate the treatment strategy utilized in these plants and find more efficient remedies.
  • One of the main causes of the decline in water quality produced by the water treatment plants in the city of Basra is management, operation, and lack of maintenance in these stations. As a result, these stations need to undergo routine maintenance, and continuous water quality checks are required.
Nomenclature

Cn

Standard maximum concentration typically provided by WHO (Table 3).

m

number of computed variables.

K

Sn

The proportionality constant.

The measured concentration of each parameter.

S0

The ideal value of each parameter in pure water. S0=0 (except pH =7.0 and Dissolved Oxygen = 14.6 mg/l).

Appendix

Appendix 1. Physical and chemical parameters (Minimum–Maximum) of water from WTPs

Parameter

Mihejran

Al-Garmma 1

Al-Jubila 1

Al-Buradiah 1

Shatt Al-Arab

Al-Zubair

Al-Fao

Al-Nashwa

Al-Qurna

Al-Ribat

Raw Water

pH

7.21-7.35

7.38-7.75

7.41-7.85

7.32-7.89

7.34-8.26

7.29-8.09

7.12-8.04

7.29-8.29

7.09-8.04

7.35-8.04

EC (µs/cm)

3379-10970

1300-5446

1356-4315

1836-5199

908-6692

1337-5030

1947-5509

1551-5808

1181-5756

871-4718

Turb.(NTU)

4.2-22.2

3-27.3

5.8-20.7

5.2-17.8

4.5-90

5.8-37.2

5-95

2.1-35.5

2.7-88

10-23

Alka. (mg/l)

148-200

128-160

130-160

124-156

120-168

120-156

142-190

122-160

126-174

120-160

TH (mg/l)

968-1880

414-1379

440-1170

576-1307

303-1288

432-1232

528-1332

472-1464

382-1392

296-1239

TDS (mg/l)

2138-7158

796-3516

818-2704

1100-3248

564-4318

822-3200

1172-3456

932-3696

726-3682

526-2964

Ca (mg/l)

198-380

86-277

86-237

122-263

62-269

88-250

112-269

96-298

78-281

59-240

Na (mg/l)

363-1880

107-701

104-488

152-616

81-1056

99-655

208-840

140-728

107-703

75-542

K (mg/l)

9.7-14.6

5.2-11.8

5-10

6-10.6

3.5-12.4

4.2-11

5-13.6

3.7-13.3

5-12.4

3-12

Cl (mg/l)

540-2860

168-1065

180-760

234-930

146-1610

150-1015

320-1275

226-1125

162-1075

136-825

Mg (mg/l)

115-227

49-168

53-141

60-158

36-150

51-148

61-161

57-175

46-168

36-150

SO4 (mg/l)

803-1723

247-1200

272-981

412-1128

141-1108

265-1033

358-1151

302-1251

216-1228

134-1074

Treated Water

pH

6.92-7.35

7.11-7.55

7.1-7.8

7.19-7.86

7.19-8.1

7.12-7.66

7.03-8

7.09-8.24

7.03-8

7.31-7.78

EC (µs/cm)

3360-10970

1273-4908

1270-4290

1824-5022

887-6680

1325-5003

1904-5916

1538-5794

1178-5748

923-4383

Turb.(NTU)

3-22.2

1.5-10.4

3.5-16.6

4.2-10.1

3-18.2

1.5-15

1.1-24.9

43101

1.2-24

2.9-12.8

Alka. (mg/l)

128-200

120-150

120-150

122-150

120-160

112-152

140-190

122-152

120-170

118-158

TH (mg/l)

952-1880

407-1194

440-1162

576-1263

303-1288

440-1216

520-1384

472-1456

382-1392

311-1178

TDS (mg/l)

2122-7158

778-3084

782-2690

1094-3132

546-4286

804-3170

1148-3682

924-3682

718-3640

568-2782

Ca (mg/l)

192-380

83-242

86-234

122-254

62-269

88-246

109-278

96-294

78-281

62-240

Na(mg/l)

358-1880

100-622

101-478

146-607

74-1043

96-644

204-889

137-725

104-696

82-510

K (mg/l)

9.5-14.6

3-13

4.7-9.6

5.7-11

3.2-12

4.2-10

5-14.4

3.5-13

5-12

3.3-11.4

Cl (mg/l)

536-2860

160-950

172-750

230-920

140-1600

146-1000

316-1375

222-1120

159-1065

136-790

Mg (mg/l)

115-227

47-144

51-141

60-153

36-150

51-147

60-168

57-176

46-168

38-177

SO4 (mg/l)

798-1723

242-1011

265-971

410-1087

138-1105

272-1018

351-1200

300-1247

214-1225

149-995

Appendix 2. Physical and chemical parameters (mean ± standard deviation) of water from WTPs

Parameter

Mihejran

Al-Garmma 1

Al-Jubila 1

Al-Bradiah 1

Shatt Al-Arab

Al-Zubair

Al-Fao

Al-Nashwa

Al-Qurna

Al-Ribat

Raw Water

pH

7.4±0.1

7.5±0.1

7.6±0.1

7.5±0.2

7.7±0.2

7.7±0.2

7.6±0.3

7.7±0.3

7.7±0.3

7.7±0.2

EC (µs/cm)

6404±2402

3204±1444

2647±868

3669±836

3103±1682

2543±1228

3440±1297

3467±1302

3282±1482

2383±1366

Turb. (NTU)

10.7±6.3

10.5±6.4

12.7±4.4

9.7±3.6

22.7±22.1

15.8±9.7

24.7±25.2

13.8±11.2

25.6±24.2

13.5±3.7

Alka. (mg/l)

175±21

141±8

142±10

143±9

142±13

137±11

156±13

143±11

148±14

138±11

TH (mg/l)

1380±309

881±328

774±220

1000±183

825±336

721±265

826±266

936±316

874±332

691±322

TDS (mg/l)

4120±1610

2003±939

1640±552

2303±530

1948±1085

1592±789

2140±853

2193±862

2046±952

1477±871

Ca (mg/l)

280±61

180±65

157±44

204±35

169±68

146±54

169±53

191±63

178±66

140±63

Na (mg/l)

929±489

351±203

265±110

406±136

357±272

271±181

435±206

394±181

371±200

242±173

K (mg/l)

12.7±1.6

8.2±2.4

7.4±1.5

9.1±1.3

8.1±3.1

6.8±2.3

8.3±2.8

8.4±2.8

8.6±2.5

7±3.3

Cl (mg/l)

1400±733

540±307

410±169

618±211

548±409

416±276

658±313

608±280

570±303

380±260

Mg (mg/l)

166±38

106±40

93±27

119±25

98±40

87±32

98±33

112±38

105±41

83±39

SO4 (mg/l)

1197±310

710±323

603±216

832±182

656±336

555±259

660±254

756±302

697±337

520±317

Treated Water

pH

7.1±0.1

7.3±0.1

7.5±0.2

7.4±0.2

7.6±0.3

7.4±0.2

7.5±0.4

7.6±0.4

7.5±0.2

7.5±0.2

EC (µs/cm)

6309±2365

2861±1376

2562±849

3631±813

3092±1678

2450±1177

3475±1448

3456±1299

3258±1488

2325±1174

Turb. (NTU)

7.4±5.6

4.2±2.9

7.4±3.8

5.5±1.7

7.1±4.5

7.2±3.9

9.3±6.4

6.1±4.9

9.4±7.6

6.6±2.8

Alka. (mg/l)

162±23

134±9

137±9

140±8

140±12

134±12

152±14

141±10

144±16

135±11

TH (mg/l)

1355±309

809±306

746±211

993±176

821±335

695±259

833±289

934±313

864±333

678±275

TDS (mg/l)

4038±1579

1833±835

1576±536

2269±519

1937±1083

1527±757

2158±941

2166±850

2020±951

1438±747

Ca (mg/l)

274±62

167±59

152±42

202±33

168±69

142±53

170±58

190±62

176±66

138±56

Na (mg/l)

911±475

304±190

253±107

399±139

354±270

260±172

440±229

390±180

365±199

235±154

K (mg/l)

12.3±1.6

7.5±3

6.9±1.4

8.8±1.4

7.8±3

6.3±2

8.4±3.3

8.2±2.8

8.3±2.4

6.8±2.6

Cl (mg/l)

1380±714

500±274

393±164

612±215

546±407

402±265

668±351

603±278

564±302

373±234

Mg (mg/l)

163±38

98±37

89±26

119±24

98±40

83±31

99±35

112±38

103±41

86±42

SO4 (mg/l)

1175±310

683±293

577±209

823±176

652±333

529±251

665±278

752±299

687±338

506±267

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