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Conductive composites of acrylamide and triethylene glycol dimethacrylate were prepared via frontal polymerization with various Raney nickel- and Pd/C content. These materials are proven to be applicable as electrodes in organic electrosynthesis. The incorporation of electrocatalytic metals results in a significant change in the chemoselectivity of the electroreduction of acetophenone, which indicates a change in the mechanism from electronation-protonation to electrocatalytic hydrogenation.
electroreduction, acetophenone, composite electrode, frontal polymerization
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