Elaboration of Composite Electrodes based on Raney Nickel- and Pd/C for Electrosynthesis Applications

Elaboration of Composite Electrodes based on Raney Nickel- and Pd/C for Electrosynthesis Applications

Dezso SzikraKrisztina Dublinszki Csaba Cserhati Istvan P. Nagy 

Department of Physical Chemistry, University of Debrecen, P.O.Box 7, H-4010 Debrecen, Hungary

Corresponding Author Email: 
deeezs@yahoo.com
Page: 
133-140
|
DOI: 
https://doi.org/10.14447/jnmes.v13i2.181
Received: 
27 February 2009
|
Accepted: 
9 December 2010
|
Published: 
9 December 2010
| Citation
Abstract: 

Conductive composites of acrylamide and triethylene glycol dimethacrylate were prepared via frontal polymerization with various Raney nickel- and Pd/C content. These materials are proven to be applicable as electrodes in organic electrosynthesis. The incorporation of electrocatalytic metals results in a significant change in the chemoselectivity of the electroreduction of acetophenone, which indicates a change in the mechanism from electronation-protonation to electrocatalytic hydrogenation.

Keywords: 

electroreduction, acetophenone, composite electrode, frontal polymerization

1. Introduction
2. Experimental
3. Results
4. Summary
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