Electrochemical studies of N,N-bis pyrazinyl • 3,4,9,10 - perylenebis (dicarboximide) (PyPD ) on Pt electrode

Electrochemical studies of N,N-bis pyrazinyl • 3,4,9,10 - perylenebis (dicarboximide) (PyPD ) on Pt electrode

E.H. El-Mossalamy A.Y. Obaid S.A. El-Daly I.S. El- Hallag A.M. Asiri L.M. Al-Harbi 

Chemistry Department, Faculty of Science, King Abdulaziz University, P. O. Box. 80203, Jeddah 21589 Saudi Arabia

Chemistry Department, Faculty of Science, Tanta University, Tanta 31527, Egypt

The Center of Excellence for Advanced Materials Research, King Abdulaziz University, P.O. Box 80203, Jeddah 21589, Saudi Arabia

Corresponding Author Email: 
ibrahimelhallag@yahoo.com
Page: 
53-57
|
DOI: 
https://doi.org/10.14447/jnmes.v16i1.53
Received: 
7 May 2012
|
Accepted: 
2 August 2012
|
Published: 
27 August 2012
| Citation
Abstract: 

The electrochemical studies of N, N – bis(pyrazinyl) – 3, 4, 9, 10 –  perylene bis (dicarboximide) (PyPD) dye has been car-  ried out on Pt electrode using cyclic voltammetry and convolution deconvolution voltammetry combined with digital simulation technique  at a platinum electrode in 0.1 mol L-1 tetrabutylammonium perchlorate (TBAP) in acetonitrile solvent (CH3CN). The compound under con- sideration was reduced via consumption of two sequential electrons to form radical anion and dianion (EE mechanism). The electrode reaction pathway and the electrochemical parameters of the investigated compound were determined using cyclic voltammetry and con- volution – deconvolution transforms. The extracted electrochemical parameters were verified and confirmed  via digital  simulation method.

Keywords: 

Perylene derivatives, Cyclic voltammetry on Pt, Convolution voltammetry, Digital simulation

1. Introduction
2. Experimental
3. Results and Discussions
4. Conclusion
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