CONSTRUCTAL LAW & THERMOECONOMICS

Page:

S141-S146

DOI:

https://dx.doi.org/10.18280/ijht.34S118

OPEN ACCESS

Abstract:

In spite of evident differences, Constructal Theory and Thermoeconomics (in particular thermoeconomic optimization) have also some similarities. For instance, they both suggest the optimal allocation of two different types of losses: high permeability vs. low permeability flow losses in the Constructal Theory, while local losses inside the process vs. external losses for making available all resources actually consumed, at local level, by a component or a process in the thermoeconomic optimization. The paper discusses this one and related aspects, highlighting how the optimal criterion of minimum energy cost of the product can be derived from the Constructal Law, when the flow of useful product through the productive structure is considered as the characteristic flow of the system. In this context, the evolution of energy systems toward highly interrelated productive structures, with recycling flows, can be regarded as a consequence of the Constructal Law.

Keywords:

*Thermoeconomics, Constructal Law, Exergy cost, Recycling.*

1. Introduction

In principle, Second Law (exergy) analysis can be applied to any kind of energy system, which is synthetically described in this approach as a network of energy flows, connecting some nodes (named components, or sub-systems) where different kinds of irreversible energy conversion processes may occur. This point of view is widely adopted for analyzing both natural, biological and ecological systems, and human-made, technological production systems [1-4].

Thermoeconomics may be regarded as a further step after exergy analysis, where external exergy destruction is taken into account for owning, maintaining and operating the components that make up a generic energy system, by means of some kind of cost [5-9]. In this approach, the exergy flows are not regarded as physical streams that flow in a real space (as is usual in the Constructal Theory approach), but rather as the functional relations among components, in the abstract space of possible productive interconnections, that make up the so called *Productive Structure* of the energy system.

In spite of these differences, Constructal Theory and Thermoeconomics (in particular thermoeconomic optimization) have also some similarities. For instance, they both pursue the optimal allocation of two different type of losses: high permeability vs. low permeability flow losses in the Constructal Theory, while local losses inside the process vs. external losses for making available all resources actually consumed, at local level, by a component or a process in the thermoeconomic optimization. These local resources include at least the energy and material flows required by the production, as well as the capital expenditure for owning, maintaining and operating the components that make up the system.

As it is evident in Literature, the Constructal Low can be used to predict the shape and structure for a lot of physical flow systems; the aim of the paper is to apply it to the *productive structure* of an energy system, in order to understand what can be inferred about the evolution of the functional relations among components.

2. A Brief Summary about The Exergy Cost

Let’s consider a steady state operation of a generic multi-component energy system and let's assume first that energy flows only are enough for completely describe its behavior (Fig. 1). If the energy flows inside the network are defined in order to properly describe the productive relations among components and with the outside of the system, each component (or process) can be regarded, at local level, as an autonomous production unit, having one output flow named *Product* or *Function* and one or more input flows, named *Fuels* or internal resources (multi-product components can be also considered, but with some restrictions about the formulation of the mathematical model of these kind of components [7]). As a result, a sort of *local model* of each component is isolated from the thermodynamic model of the whole system, while the network obtained can be regarded as the so called *Productive Structure* (PS) of the system. Each flow *E _{i}* describing a

Let’s consider the basic question: How much primary energy (or better, exergy) has been used by the macro-system to maintain each flows of the PS at a defined value? If the system is similar to a linear chain (like the one in Fig.1) and it is operating in stationary condition, the answer can be easily inferred [10]. In fact, flows *E _{1}* and

primary energy *F _{1}* and

Let’s think at the bifurcation of flow *E _{3}* as a split, without any thermodynamic transformation or process, therefore the flow E

**Figure 1.** A simple linear system with a split

The ratios like *F _{1}/ E_{3}* º

$\boldsymbol{E}=^{t} \boldsymbol{K} \boldsymbol{E}+\boldsymbol{\omega}$(1)

$\boldsymbol{k}^{*}=\left[\boldsymbol{U}_{D}-\boldsymbol{K}\right]^{-1} \cdot \boldsymbol{k}_{e}^{*}$(2)

where ** K** is a square matrix containing the specific exergy consumptions

In principle, the approach could be the same also if some incoming resources were not energy or material resources (measured by their exergy content), but capital expenditure for owning, maintaining and operating the components that make up the system. These kind of production factors are generally not known in term of their exergy content, or exergy cost, but they can be easily converted in monetary flows [€/s], so that the classical thermoeconomic approach prescribes to transform all costs in monetary flows by means of the *unit monetary costs* of all energy and material inputs.

In alternative, accounting methods based solely on exergy have been proposed by various Authors, beginning by Szargut [11, 12] and today the option of defining an exergy equivalent of money is widely accepted and adopted in literature [13, 14]. The idea that an exergy equivalent of money can be defined and used in exergy cost accounting will be taken into account in the following, without further considerations (an interesting discussion about accounting methods based solely on exergy and the proper definition of the exergy equivalent of money, for a generic economy, is reported in [15]).

3. Unit Exergy Cost and Constructal Law

Let’s consider the component producing the flow *E _{3 }*in Fig. 1 and consuming the flow

$\frac{E_{3}}{F_{1}}=\frac{1}{k_{3}^{*}}$(3)

This result can be easily demonstrated for all flows in whatever productive structure, provided that the unit exergy costs (*k ^{*}_{i}*) are obtained from eq. (2); it can be also inferred that:

$\frac{P_{j}}{I_{T O T_{j}}}=\frac{1}{k_{j}^{*}-1}$(4)

where *I _{TOTj}* is the total exergy destruction caused by the production of the flow

$I_{E X T_{j}}=\sum_{i}\left(k_{j}^{*}-1\right) E_{i}$(5)

In addition, it can be also inferred that the external exergy destruction for producing *P _{j}* is greater than the internal one if the unit exergy cost

$k_{j}^{*} \geq 2 \sum_{i}\left(\kappa_{i j}-1\right)$(6)

As it is well known, the Constructal Law, proposed by Bejan in 1996, states [16]:

For a finite-size flow system to persist in time (to live), its configuration must evolve in such a way that provides greater and greater access to the currents that flow through it.

If the *current that flow through* the energy system is identified with its useful product (per unit of primary exergy resources consumed) the Constructal Law prescribes an evolution toward a product increase, i.e. (in thermoeconomic terms) an evolution toward a reduction of the unit exergy cost of the product (Eq. 3). This is exactly the aim of the thermoeconomic analysis. In other words, the axiom of thermoeconomic analysis: *reduce the unit exergy cost of the products*, can be inferred from the Constructal Law if the energy system is described in thermoeconomic terms and the current that flow through it is identified with the flow of its useful product.

Let’s consider now a generic real energy system: it is straightforward to think that it does not operate in an empty space (like the system in Fig. 1) but that it is surrounded by a biosphere (or an anthroposphere) where different kinds of resources are available at different unit exergy costs and with different constraints about their availability in time and space. This way of thinking may be named as *the system in its thermoeconomic environment*. In order of reducing the unit exergy cost of its product, the system may evolve to reduce its specific exergy consumptions of local resources (*k** _{ij}*), or it can modify its supply chain, using resources with a lower unit exergy cost. Neither of these strategies should be preferred over the other, because the internal irreversibility can be either greater or smaller than the external ones, as can be inferred from Eq. 6.

4. Constructal Law and Thermoeconomic Optimization

To illustrate the evolution of a possible energy system in its thermoeconomic environment, the framework shown in Fig.2 is considered. In particular, a solar system, made up of three sub-systems, is highlighted inside the dashed rectangle. Natural resources (*E _{2}*) are used, after extraction and transportation (

The thermoeconomic environment includes three big sub-systems only: the *fuel industry*, supplying fossil fuel (*E _{5}*) for extraction and transportation of row mineral resources, for the industrial plant production (

Notice that, in this illustrative example, the exergy equivalent of money can be calculated from the cost balance of the industrial plant production, given that fixed capital is taken into account by means of monetary flows [€/s], calculated on the same time basis of the exergy flows.

**Figure 2.** A solar energy system in a possible thermoeconomic environment

A lot of other sub-systems and productive relations could be added, in order of defining a more meaningful thermoeconomic environment, but they are outside of the objectives of the illustrative example. For the same reason, the actual values of the flows in Fig. 2 are not of interest.

**Figure 3. **Relation used for evaluating the fixed capital *Z _{2 }*and the corresponding values of the unit exergy cost

To show some kind of evolution, consistent with the Construcal Law, let’s assume in the following that the thermoeconomic environment outside the solar system does not vary, whilst the solar system can modify the fixed capital (*Z _{2}*) and the electric power (

$\frac{Z_{2}}{E_{6}}=\frac{1}{\left(\frac{E_{7}}{E_{6}}\right)^{n}} \frac{m}{\left(\frac{E_{1}}{E_{8}}\right)-\frac{1}{\eta_{M}}}$(7)

where *n* and *m* are proper constants and *h** _{M }*is the maximum possible efficiency considered. In Fig. 3, Eq. 7 is reported in form of curves

Let’s consider a starting workable condition (A), where the solar system is based on an energy conversion phase with an efficiency *h** _{8 }*= 12%. As can be seen in Fig.3, the electric power

As shown in the previous paragraph, the Constructal Law prescribes an evolution of the system toward a condition allowing lower unit exergy costs to be obtained. This can be achieved approaching condition (B), which is the minimum of the curve at constant parameter *h** _{8 }*= 12%, therefore it can be identified as the optimal trade-off between the capital intensity and the energy intensity of the production process, without modifying the energy conversion efficiency

In the Constructal Law language, it would be said that the optimal allocation of two different types of losses has been obtained in the optimal thermoeconomic condition (B): local losses inside the control volume of the system vs. external losses in the thermoeconomic environment, for making available all resources actually consumed by the system itself. Therefore, this result can be regarded as analogous to the optimal allocation of losses between high permeability and low permeability flows in a river basin, or in a lot of other tree shaped structure, obtained in Literature on the basis of the Constructal Law (see, for instance [16] and the references reported there).

In the example in hand, the optimal thermoeconomic condition (B) requires a lower energy intensity and a higher capital cost, but this is related with the starting workable condition (A) on the right hand side of point (B).

Going on towards lower and lower unit exergy costs of the power produced, implies a technological development (or an improved energy conversion strategy) allowing the system to achieve a higher energy conversion efficiency* h** _{8}*.

In the example shown in Fig. 3, an energy conversion efficiency* h** _{8 }*= 20% allows a further reduction of the unit exergy cost

5. Constructal Law and Energy Recycling

Notice that in condition (C) in Fig. 3, the unit exergy cost *k ^{*}_{8}* has reached a value as low as the reference value

along with the evolution from condition (A) to condition (C), or *split* *the product* *E _{8}* of the solar energy system itself in two flows, the first one for the power users and

It can be easily shown that a further improvement of the energy conversion efficiency (for instance,* h** _{8 }*= 25%) allows a further reduction of the unit exergy cost

**Figure 4.** The unit exergy cost *k* _{8}*, with and without the partial recycling of flow

This is an important point, because it means that, once the recycling flow has arisen, the selection criteria expressed by the Constructal Law works in the direction of reinforcing the recycling flow itself.

Notice that such conclusions can be inferred in force of the framework of the system in its thermoeconomic environment, where different kinds of resources are available at different unit exergy costs and with different constraints about their availability in time and space. In this framework the system is free, subject to the mentioned constraints, of switching to use local resources at a lower unit exergy cost, so as to increase its flows of useful product (per unit of primary exergy resource consumed), as prescribed by the Constructal Law. If the energy system is supposed to operate inside an empty space, there are no choice about the local resources to be employed, and the Constructal Law does not find any degree of freedom to morph the productive structure and to make the recycling arise.

In the previous paragraph, the hypothesis has been introduced stating that the production of solar energy conversion systems with higher efficiencies implies an higher consumption of local resources (capital and/or exergy). Finally, notice that, if this hypothesis were replaced with a different one implying constant, or even lower, consumption of local resources, the recycle would arise even more easily.

Taking into account that in a real energy system the chance for introducing recycling flows are much more, the expectation is that these results could be extended to all generic energy systems (both technological and biological) stating:

The Constructal Law prescribes the evolution of energy systems toward highly interrelated productive structures, with multiple recycling flows, at different hierarchical level.

6. Conclusions

The Constructal Law can be used to predict the shape and structure of a lot of physical flow systems; in this paper it has been applied it to the *productive structure* of an energy system, in spite of being the latter a network of functional relations among components (in the abstract space of possible productive interconnections), rather than a stream of physical flows.

If the energy system is described thought its *productive structure*, as in the thermoeconomic approach, and the current that flows through it is identified with its useful product (per unit of primary exergy resources consumed), the Constructal Law prescribes an evolution toward a reduction of the unit exergy cost of the product, that is strictly consistent with the aim of the thermoeconomic analysis.

This can be achieved approaching the optimal allocation of two different types of losses: local losses inside the control volume of the system vs. external losses in the thermoeconomic environment, for making available all resources actually consumed by the system itself. In the thermoeconomic language, this is the optimal trade-off between the capital investment and the exergy destruction of the production process, and corresponds to the thermoeconomic optimization of the system.

In consequence of the evolution prescribed by the Constructal Law, it has been highlighted that recycling flows may arise in the productive structure and, once a recycling flow has arisen, the selection criteria expressed by the Constructal Law works in the direction of reinforcing the recycling flow itself. In this process, a crucial role is played by the framework of the thermoeconomic environment, because, if there are no choices about the local resources to be employed, the Constructal Law does not find any degree of freedom to morph the productive structure and to make the recycling arise.

In the outlined context, the evolution of energy systems toward highly interrelated productive structures, with multiple recycling flows, can be regarded as a consequence of the Constructal Law.

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