Study of Relaxation and Dielectric Response of Polyimide Films

Study of Relaxation and Dielectric Response of Polyimide Films

Fadila Benabed Taher Seghier Saliha Boudraâ Abdellatif Seghiour Mohamed Benabdallah Taouti Salem Fouad Chabira

Laboratoire d’étude et de développement des matériaux semi-conducteurs et diélectriques (LED MASD) Université Amar Telidji, Laghouat, Algérie

Corresponding Author Email: 
benabed_fa@yahoo.fr
Page: 
79-93
|
DOI: 
https://doi.org/10.3166/EJEE.18.79-93
Received: 
8 July 2015
| |
Accepted: 
22 January 2016
| | Citation

OPEN ACCESS

Abstract: 

In recent years, polyimides are more and more used as high performance polymers because of their excellent thermal, mechanical and electrical properties. In this work, dielectric properties and relaxation behavior of some Polyimide films were studied on the basis of dielectric constant, dielectric loss and AC conductivity taking into account their variation with frequency and temperature. According to the results, three types of relaxations α, β and γ at decreasing temperature were detected, the origin of these relaxations and the influence of the chemical structure on changes in dielectric and electrical properties were discussed.

Keywords: 

dielectric relaxation, polyimide, dielectric spectroscopy.

1. Introduction
2. Experimental Method
3. Results and Discussions
4. Conclusion
  References

Arnold F.E., J. R., Bruno K.R., Shen D., Eashoo M., Lee C.J., Harris F.W, Cheng S.Z.D. (1993). The Origin of β-Relaxations in Segmented Rigid-Rod Polyimide and Copolyimide Film, Polymer Engineering and Science, 33, 1373.

Bas C., Albérola N.D., Tamaga C., Pascal T. (1999). Influence de la structure chimique de la séquence diimide sur la relaxation γ des polyimides, C. R. Acad. Sci. Paris, t. 327, Série II B, Physicochimie, p. 1095-1100.

Benabed, F., Seghier T., Boudraâ. S., Seghiour A. (2014). Dielectric Proprieties and R elaxation Behavior of Polyimide Films ( PI ). IEEE procedeeng of Electrical Sciences and Technologies in Maghreb (CISTEM), Tunis, p. 234-237

Cheng S.Z.D., Chalmers T. M., Gu Y., Yoon Y., Harris F. W. Cheng J. (1995). Fone M., Koenig J. L. Jack. (1995). Relaxation processes and molecular motion in a new semicrystalline polyimide, Macromol. Chem. Phys. 196, p. 1439-1451, 1439

Chi K. K. (2004). Dielectric phenomena in solids: with emphasis on physical concepts of electronic processes, Elsevier Academic Press, USA, p. 94-97.

Chisca S., Sava I., Musteata V.E., Bruma M. (2011). Dielectric and Conduction Properties of Polimides Films, IEEE. CAS 2011 Proceedings (2011 International Semiconductor Conference), p. 253-256

Chisca S., Musteata V.E., Sava I., Bruma M. (2011). Dielectric behavior of some aromatic polyimide films, European Polymer Journal, 47, p. 1186-1197.

Dasari M.P., Sambasiva Rao K., Murali Krishna P., Gopala Krishna G. (2011). Barium Strontium Bismuth Niobate Layered Perovskites: Dielectric, Impedance and Electrical Modulus Characteristics, Acta Physica Polonica A. vol. 119, n° 3, p. 387-394.

David Jacobs J., Arlen M. J., Wang D.H., Ounaies Z., Berry R., Tan L. S., Garret P. H., Vaia R. A. (2010). Dielectric characteristics of polyimide CP2, Polymer 51, p. 3139- 3146.

Deligöz H, Yalcinyuva T, Özgümüs S, Yildirim S. (2006). Electrical properties of conventional polyimide films: effects of chemical structure and water uptake. J Appl Polym Sci, 100:p. 810-818.

Diaham S., Locatelli M.L., Lebey T, Dinculescu S. (2009). Dielectric and Thermal Properties of Polyamide-Imide (PAI) films, Annual report Conference on Electrical Insulation and dielectric Phenomena, p. 482-485.

Diaham S. (2007). Etude du comportement sous haute température de matériaux polyimides en vue de la passivation de composants de puissance à semi-conducteur grand Gap. Thèse en Génie Electrique, Université Toulouse III - Paul

Sabatier. Hamciuc C., Hamciuc E., Olariub M., Ciobanub R. (2010). Thermal and electrical behavior of some hybrid polyimide films containing barium and titanium oxides, Polymer International, vol. 59, n° 5, p. 668-675.

Ishida, H.; Wellinghoff, S.T.; Baer, E.; Koenig J.L. (1980). Spectroscopic studies of poly(N,N’-bis(phenoxyphenyl) pyromellitimide). 1. Structures of the polyimide and three model compounds. Macromolecules, 13, 826-834

Jonscher A. K. (1983). Dielectric Relaxation in solid. Chelsea Dielectric Press, London, p. 214.

Jonscher A.K. (1981). Review Anew understanding of the dielectric relaxation of solids. Journal of Materials Science, 16, p. 203-2060.

Kum-PyoY., Myung Jin L., Kwang-Ho K., Jaehwa J., Nam-Ki M. (2010). Dielectric properties of on-chip-cured polyimide films, Thin Solid Films, 518, p. 5986-5991

Liaw D.J, Wang K.L., Huang Y.C., Lee K.R., Lai J.Y., Ha C.S. (2012). Advanced polyimide materials: Syntheses, physical properties and applications, Progress in Polymer Science, 37, p. 907-974.

Muruganand S., Narayandass Sa. K., Mangalaraj D., Vijayan TM. (2001). Dielectric and conduction properties of pure polyimide films. Polymer International, 50, p. 1089- 1094.

Ngai K.L., Paluch M. (2004). Classification of Secondary Relaxation in Glass-Formers Based on Dynamic Properties, Journal of Chemical Physics, 120, 857.

Papathanassiou A.N. (2006). Novel feature of the universal power law dispersion of the ac conductivity in disordered matter, Journal of Non-Crystalline Solids, 352, p. 5444- 5445.

Pham C.D., Wei L., Locatelli M.L, Diaham S. (2013). Dielectric relaxation spectroscopy of single- and double-layer polyimide/SiO2 thin films, 2013 IEEE International Conference on Solid Dielectrics, Bologna, Italy, June 30-July 4.

Qiu F. X., Li P. P., Yang D. Y. (2007). Synthesis, characterizations and electro-optical properties of nonlinear optical polyimide/silica hybrid, eXPRESS Polymer Letters, vol. 1, n° 3, p. 150-156, www.expresspolymlett.com DOI: 10.3144/expresspolymlett.

Raju G. G. (2003). Dielectrics in Electric Fields, New York: Marcel Dekker Inc. Schonhals. A., Kremer. F. (2003). Analysis of dielectric spectra. In: Kremer F, Schönhals A, editors.Broadband Dielectric Spectroscopy.Berlin:Springer-Verlag, p. 59-98. Sroog C. E. (1991). Polyimides, Prog. Polym. Sci., vol. 16, p. 561-694.

Sun Z., Dong L., Zhuang Y., Cao L., Ding M., Feng Z. (1992). Beta Relaxation in Polyimides, Polymer, 33, 4728.

Williams G. (1982). Dielectric relaxation of solid polymers, Static and Dynamic Properties of the Polymeric Solid State, p. 213-239.

Xie S., Zhang Z., Wei W. (2007). Synthesis and Properties of Polyimide-Based Optical Materials, Journal of the Korean Physical Society, vol. 51, n° 4,

October, p. 1536- 1541 Xu G., Gryte C.C., Nowick A.S., Li S.Z., Pak Y.S., Greenbaum S.G. (1989). Dielectric Relaxation and Deuteron NMR of Water in Polyimide Film, Journal of Applied Physics, 66, 5290.

Xu Y. K., Zhan M. S., WANG K. (2004). Structure and Properties of Polyimide Films during a Far- Infrared-Induced Imidization Process, Journal of Polymer Science: Part B: Polymer Physics, vol. 42, p. 2490-2501

Zhigao L., Bonnet J.P., Ravez J., Hagenmuller P. (1992). Solid State Ionics, 57, 235